Synthesis, crystal structure and thermal stability property of Ni(aze)(4,4′ –bipy)(H2O) based on longer-spanning azelaic acid and 4,4′ -bipyridine ligands
نویسندگان
چکیده
One new three-dimensional (3D) supramolecular longer-spanning azelaic acid (H2aze) complex: Ni(aze)(4,4′– bipy)(H2O) (4,4′-bipy = 4,4′-bipyridine) has been synthesized using hydrothermal conditions and characterized by elemental analysis, IR spectroscopy, UV spectrum, powder X-ray diffraction, TG analysis and single crystal X–ray diffraction. Structural analysis reveals that the title complex is six-coordinate and connected by the azelaic acid and 4,4′-bipy ligands to generate a 2D planar structure, further linked through the interaction of hydrogen bond of C–H···O to form a 3D supramolecular structure. Supporting information: FT-IR, UV-Vis, X-Ray, Cif file
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Utilization of mixtures of aromatic N-donor ligands of different coordination ability for the solvothermal synthesis of thiostannate containing molecules.
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